Organically modified montmorillonite composited with magnetic glyoxal-chitosan Schiff base for reactive blue 19 dye removal: Process optimization and adsorptive mechanism

Ahmed Saud Abdulhameed; Ahmad Hapiz; Salis Auwal Musa; Elmira Kashi; Ruihong Wu; Zeid A ALOthman; Ali H Jawad; Sameer Algburi

doi:10.1016/j.ijbiomac.2023.128463

Organically modified montmorillonite composited with magnetic glyoxal-chitosan Schiff base for reactive blue 19 dye removal: Process optimization and adsorptive mechanism

Int J Biol Macromol. 2024 Jan;256(Pt 2):128463. doi: 10.1016/j.ijbiomac.2023.128463. Epub 2023 Nov 28.

Authors

Ahmed Saud Abdulhameed¹, Ahmad Hapiz², Salis Auwal Musa², Elmira Kashi², Ruihong Wu³, Zeid A ALOthman⁴, Ali H Jawad⁵, Sameer Algburi⁶

Affiliations

¹ Department of Pharmaceutical Chemistry, College of Pharmacy, University of Anbar, Ramadi, Iraq; College of Engineering, University of Warith Al-Anbiyaa, Karbala, Iraq.
² Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Advanced Biomaterials and Carbon Development Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia.
³ Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Advanced Biomaterials and Carbon Development Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Department of Chemistry, Hengshui University, 053500, Hebei Province, Hengshui, China.
⁴ Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia.
⁵ Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Advanced Biomaterials and Carbon Development Research Group, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; Environmental and Atmospheric Sciences Research Group, Scientific Research Center, Al-Ayen University, Thi-Qar, Nasiriyah 64001, Iraq. Electronic address: ali288@uitm.edu.my.
⁶ College of Engineering Technology, Al-Kitab University, Kirkuk, Iraq.

PMID: 38029908
DOI: 10.1016/j.ijbiomac.2023.128463

Abstract

In this study, a new biocomposite magnetic adsorbent (magnetic glyoxal-chitosan Schiff base/organically modified montmorillonite (MCTS-GOX/OMMT)) was synthesized and employed for the adsorption of reactive blue 19 dye (RB19) from aqueous environment. The physicochemical properties of the MCTS-GOX/OMMT were confirmed by using various characterization techniques such as BET, XRD, FTIR, SEM-EDX, VSM, and pH_pzc. The adsorption key variables were statistically optimized via Box-Behnken design (BBD) And accordingly the best operational conditions to achieve maximum RB19 removal were recorded at MCTS-GOX/OMMT dosage = 0.1 g/0.1 L, solution pH = 4, and working temperature = 25 °C. The adsorption process for RB19 appeared to follow the pseudo-second-order kinetic and the Langmuir isotherm models, according to the findings of the adsorption kinetics and equilibrium investigations. The maximum adsorption capacity of the MCTS-GOX/OMMT towards RB19 was 122.3 mg/g, demonstrating its preferable adsorption capability. The successful development of this novel magnetic bioadsorbent with excellent adsorption ability towards organic dyes and efficient separation ability opens possibilities for its practical application in wastewater treatment and dye removal processes.

Keywords: Chitosan; Organically modified montmorillonite; Schiff's base.

MeSH terms

Adsorption
Anthraquinones*
Bentonite
Chitosan* / chemistry
Coloring Agents
Glyoxal / chemistry
Hydrogen-Ion Concentration
Kinetics
Magnetic Phenomena
Schiff Bases / chemistry
Water Pollutants, Chemical* / chemistry

Substances

Chitosan
Remazol Brilliant Blue R
Bentonite
Coloring Agents
Schiff Bases
Glyoxal
Water Pollutants, Chemical
Anthraquinones