Degree of conversion and physicomechanical properties of newly developed flowable composite derived from rice husk using urethane dimethacrylate monomer

Proc Inst Mech Eng H. 2023 Dec;237(12):1339-1347. doi: 10.1177/09544119231208222. Epub 2023 Nov 28.

Abstract

This study evaluated the use of urethane dimethacrylate (UDMA) as a base monomer to prepare the newly developed flowable composite (FC) using nanohybrid silica derived from rice husk in comparison to bisphenol A-glycidyl methacrylate (Bis-GMA) on the degree of conversion and physicomechanical properties. The different loadings of base monomer to diluent monomer were used at the ratio of 40:60, 50:50, and 60:40. The bonding analysis confirmed the presence of nanohybrid silica in the newly developed FC. Independent t-test revealed a statistically significant increase in the degree of conversion, depth of cure and Vickers hardness of the UDMA-based FC, while surface roughness showed comparable results between the two base monomers. In conclusion, UDMA-based FC demonstrated superior performance with 60%-65% conversions, a significantly higher depth of cure exceeding 1 mm which complies with the Internal Standard of Organization 4049 (ISO 4049), and a substantial increase in Vickers hardness numbers compared to Bis-GMA-based FC, making UDMA a suitable alternative to Bis-GMA as a base monomer in the formulation of this newly developed FC derived from rice husk.

Keywords: Nanohybrid; bisphenol A-glycidyl methacrylate; flowable composite; silica; urethane dimethacrylate.

MeSH terms

  • Bisphenol A-Glycidyl Methacrylate
  • Composite Resins
  • Materials Testing
  • Oryza*
  • Polyethylene Glycols
  • Polymethacrylic Acids
  • Polyurethanes
  • Silicon Dioxide

Substances

  • urethane dimethacrylate luting resin
  • flowable hybrid composite
  • Bisphenol A-Glycidyl Methacrylate
  • Polymethacrylic Acids
  • Polyethylene Glycols
  • Composite Resins
  • Polyurethanes
  • Silicon Dioxide