This study aimed to assess the potential of sewage sludge, a significant residue of wastewater treatment plants (WWTPs), as a sustainable resource for producing a bio-based material for hermetic bags (BMHB), in order to reduce the dependency on petroleum-derived plastics. The approach involved the application of thermal hydrolysis to solubilize sewage sludge, and it systematically examined critical process parameters, including temperature (120-150 °C), residence time (1-4 h), and medium pH (6.6-10). Results revealed that alkaline thermal hydrolysis significantly enhanced biomolecule solubilization, particularly proteins (289 ± 1 mg/gVSSo), followed by humic-like substances (144 ± 6 mg/gVSSo) and carbohydrates (49 ± 2 mg/gVSSo). This condition also increased the presence of large-and medium-sized compounds, thereby enhancing BMHB mechanical resistance, with puncture resistance values reaching 63.7 ± 0.2 N/mm. Effective retention of UV light within the 280-400 nm range was also observed. All BMHB samples exhibited similar properties, including water vapor permeability (WVP) (∼3.9 g * mm/m2 * h * kPa), hydrophilicity (contact angles varied from 35.4° ± 0.3 to 64° ± 5), solubility (∼95%), and thermal stability (∼74% degradation at 700 °C). Notably, BMHB proved to be an eco-friendly packaging for acetamiprid, an agricultural pesticide, preventing direct human exposure to harmful substances. Testing indicated rapid pesticide release within 5 min of BMHB immersion in water, with only 5% of BMHB residues remaining after 20 min. Additionally, the application of this material in soil was considered safe, as it met regulatory limits for heavy metal content and exhibited an absence of microorganisms.
Keywords: Bio-based material; Biopolymers; Eco-friendly packaging; Sewage sludge; Thermal hydrolysis.
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