Enhancing the multifunctional properties of cellulose fabrics through in situ hydrothermal deposition of TiO2 nanoparticles at low temperature for antibacterial self-cleaning under UV-Vis illumination

Abstract

This study aimed to improve the multifunctional properties (including photocatalysis, stability reusability, self-cleaning, antibacterial effects, and thermal radiation shielding) of cellulose fabrics through incorporation of TiO₂ nanoparticles. To achieve this, anatase TiO₂ nanoparticles were synthesized in situ and deposited onto cotton fabrics through hydrothermal method. The presence of TiO₂ nanoparticles in cellulose fabrics greatly enhanced the photocatalytic efficiency and adsorption range and did not damage the fabric fibers. The TiO₂-coated cotton exhibited an outstanding photocatalytic efficiency, with dye removal rates of 92.20 % ± 0.015 % and 99.68 % ± 0.002 % under UV-A and visible illumination, respectively. In addition, the material exhibited thermal radiation shielding properties, in which no heat absorption was observed within 60 min at 40 °C-70 °C. To further enhance the hydrophobicity, the TiO₂-coated cotton was surface-modified with 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTS). The resulting PFDTS/TiO₂-coated cotton was superhydrophobic with a water contact angle of 156.50° ± 0.05° with a sliding angle of 4.33° ± 0.47° and roughness of 67.35 nm. The superhydrophobicity of the PFDTS/TiO₂-coated cotton also facilitated self-cleaning through water injection to remove soil impurities. Furthermore, the PFDTS/TiO₂-coated cotton exerted antibacterial effects against gram-negative (Escherichia coli) and gram-positive (Staphylococcus aureus) bacteria under UV-A or visible illumination. These nanocomposite fabrics with multifunctional properties have potential for industrial, military, and medical applications.

Keywords: Antibacterial; Photocatalytic activity; Titanium dioxide.