We build a model to elucidate the high harmonic generation in combined EUV and midinfrared laser fields by embodying the spin-resolved three-electron dynamics. The EUV pulse ionizes an inner-shell electron, and the midinfrared laser drives the photoelectron and steers the electron-ion rescattering. Depending on the spin of the photoelectron, the residual ion including two bound electrons can be either in a single spin configuration or in a coherent superposition of different spin configurations. In the latter case, the two electrons in the ion swap their orbits, leading to a deep valley in the harmonic spectrum. The model results agree with the time-dependent Schrödinger equation simulations including three active electrons. The intriguing picture explored in this work is fundamentally distinguished from all reported scenarios relied on spin-orbit coupling, but originates from the exchanges asymmetry of two-electron wave functions.