In this study, we examined the early-stage interaction of three types of slag and six activators with different chemical compositions. To determine the degree of hydration (DOH) and hydrate assemblage in alkali-activated slag (AAS), we employed EDX, XRD, and NMR analyses. We found that with increasing silicate concentration in the activator, the DOH in the AAS varied, whereas the proportion of C-(N)-A-S-H increased and the other Al-containing phase decreased. When examining the impact of the activator on glass dissolution, it is apparent that an index based on the degree of depolymerization of the glass structure correlates with the DOH and the proportion of hydrotalcite in the AAS. Coupled with the activator's modulus, this index can be utilised to elucidate the dissolution-reprecipitation mechanism that governs the interaction between the activator and slag.
Keywords: alkali-activated slag; dissolution–reprecipitation mechanism; non-bridging oxygen model; water glass.