SnAg2O3-Coated Adhesive Tape as a Recyclable Catalyst for Efficient Reduction of Methyl Orange

Materials (Basel). 2023 Oct 31;16(21):6978. doi: 10.3390/ma16216978.

Abstract

Silver oxide-doped tin oxide (SnAg2O3) nanoparticles were synthesized and different spectroscopic techniques were used to structurally identify SnAg2O3 nanoparticles. The reduction of 4-nitrophenol (4-NP), congo red (CR), methylene blue (MB), and methyl orange (MO) was studied using SnAg2O3 as a catalyst. Only 1.0 min was required to reduce 95% MO; thus, SnAg2O3 was found to be effective with a rate constant of 3.0412 min-1. Being a powder, SnAg2O3 is difficult to recover and recycle multiple times. For this reason, SnAg2O3 was coated on adhesive tape (AT) to make it recyclable for large-scale usage. SnAg2O3@AT catalyst was assessed toward MO reduction under various conditions. The amount of SnAg2O3@AT, NaBH4, and MO was optimized for best possible reduction conditions. The catalyst had a positive effect since it speed up the reduction of MO by adding more SnAg2O3@AT and NaBH4 as well as lowering the MO concentration. SnAg2O3@AT totally reduced MO (98%) in 3.0 min with a rate constant of 1.3669 min-1. These findings confirmed that SnAg2O3@AT is an effective and useful catalyst for MO reduction that can even be utilized on a large scale for industrial purposes.

Keywords: SnAg2O3; SnAg2O3@AT; methyl orange; nanocatalyst; pollutants; reduction.

Grants and funding

The Deanship of Scientific Research (DSR) at King Abdulaziz University (KAU), Jeddah, Saudi Arabia has funded this project under grant no. (G: 529-247-1443).