The tunable optical display is vital for many application fields in telecommunications, sensors, and military devices. However, most optical materials have a strong wavelength dependence, which limits their spectral operation range. In this work, we develop an electrically reconfigurable optical medium based on graphene, demonstrating a cycle-controlled display covering the electromagnetic spectrum from the visible to the infrared wavelength. Through an electro-intercalation method, the graphene-based surface enables rich colors from gray to dark blue to dark red to yellow, and the response time is about 1 min from the start gray color to the final yellow color. Simultaneously, it exhibits a remarkable change in infrared emissivity (from 0.63 to 0.80 reduction to 0.20) with a response time of 1 s. This modification of optical properties of lithiated multilayer graphene (MLG) is the increase of Fermi energy (Ef) due to the charge transfer from lithium (Li) to graphene layers, which causes changes in interband and intraband electronic transitions. Our findings imply potential value in fabricating multispectral optical materials with high tunability.
Keywords: intercalation; multilayer graphene; optical display; patterned electrode; tunable.