Isolation of (Aryl)-(Imino) Phosphide and (Aryl)-(Phosphaalkene) Amide Complexes of Alkali Metals from Carbene-Phosphinidenes under Reductive-Thermal Rearrangements

Ekta Nag; Maria Francis; Divya Putta; Sudipta Roy

doi:10.1002/chem.202303433

Isolation of (Aryl)-(Imino) Phosphide and (Aryl)-(Phosphaalkene) Amide Complexes of Alkali Metals from Carbene-Phosphinidenes under Reductive-Thermal Rearrangements

Chemistry. 2023 Nov 21;29(65):e202303433. doi: 10.1002/chem.202303433. Epub 2023 Nov 7.

Authors

Ekta Nag¹, Maria Francis¹, Divya Putta¹, Sudipta Roy¹

Affiliation

¹ Department of Chemistry, Indian Institute of Science Education and Research (IISER), Tirupati, 517507, India.

PMID: 37933716
DOI: 10.1002/chem.202303433

Abstract

Invited for the cover of this issue are Sudipta Roy and co-workers at the Indian Institute of Science Education and Research (IISER) Tirupati. The image depicts the rearrangement of cyclic alkyl(amino) carbene (cAAC)-supported chloro-phosphinidenes affording two ligands, of which one was used for the solid-state isolation of three cyclic alkyl(amino-boryl) phosphaalkenes and two coinage metal clusters. Read the full text of the article at 10.1002/chem.202302120.