Effects of suspended particles and dispersants on marine oil snow formation of crude oil/diesel oil

Environ Sci Pollut Res Int. 2023 Dec;30(57):119847-119862. doi: 10.1007/s11356-023-30670-x. Epub 2023 Nov 6.

Abstract

Marine oil snow (MOS) potentially forms after an oil spill. To fully understand the mechanism of its formation, we investigated the effects of suspended particles (SP) and dispersants on MOS formation of crude oil and diesel oil by laboratory experiments. In the crude oil experiment, the SP concentration of 0.2 g L-1 was more suitable for crude oil MOS formation. The addition of dispersants significantly stimulated N and TV during MS/MOS formation of SP at 0.4 g L-1 and 0.8 g L-1 concentration (p < 0.05). Without SP, the dispersants also stimulated crude oil MOS formation. Furthermore, the concentration of SP had a significantly positive effect on the reduction of the total amount of N-alkanes (p < 0.05). In the diesel oil experiment, after adding dispersants to diesel oil, the maximum N, Dm, and TV values at a SP concentration of 0.2 g L-1 were significantly higher than those at 0.4 g L-1 and 0.8 g L-1 (p < 0.05). Besides, we found that dispersants stimulated MOS formation in diesel oil at a SP concentration of 0.2 g L-1. However, the dispersants had an inhibitory effect on diesel oil MOS formation without SP. Notably, the MOS formed by diesel oil appeared white, unlike the black MOS associated with crude oil. These findings are important for the environmental impact of oil spills and elevated SP concentrations.

Keywords: Dispersants; Marine oil snow; Oil spill; Suspended particles.

MeSH terms

  • Alkanes
  • Geologic Sediments
  • Petroleum Pollution* / analysis
  • Petroleum*
  • Surface-Active Agents
  • Water Pollutants, Chemical* / analysis

Substances

  • Petroleum
  • Water Pollutants, Chemical
  • Alkanes
  • Surface-Active Agents