Assessing flux and primary sources of the atmospheric nitrogen (N) deposition with high spatial resolution remained challenging. The epilithic moss is considered a suitable biological monitor to explore N deposition. Our study presented a detailed analysis of flux and major source contributions of ammonium (NH4+) and nitrate (NO3-) deposition using N and δ15N signatures of epilithic moss collected densely from the Yangtze River basin. The results showed a more negative δ15N and higher N concentration of the moss in cropland and urban area than in forest and grassland of the basin. A gradient of the estimated N deposition (9.6-34.0 kg ha-1 yr-1) occurred from the Tibetan Plateau to lower reaches, with amount of NH4+ was approximately three times higher than NO3- deposition. The contribution from volatilization to NH4+ deposition (33.28 ± 8.10%) was less than the contribution from combustion (66.72 ± 8.10%), inconsistent with the traditional findings that N fertilizer and livestock waste are the principal sources of NH3 emissions. Fossil fuel was the dominant sources of NO3- deposition, accounted for 70.22 ± 18.67%. From 2006 to 2019, the source contribution of N deposition in forest remained unchanged, while NH3 volatilization and fossil fuel emitted NOx in urban areas have increased. Our findings highlighted the importance of combustion sources to N deposition in the Yangtze River basin.
Keywords: Biological monitors; Epilithic moss; Mass-balance mixing model; Nitrogen deposition; Source contributions.
Copyright © 2023 Elsevier Ltd. All rights reserved.