Photoinduced large magnetic change at room temperature and radical-quenched spin glass in a cyanide-bridged MnII-FeIII compound

Li-Zhen Cai; Xiao-Qing Yu; Ming-Sheng Wang; Guo-Cong Guo

doi:10.1039/d3dt03080f

Photoinduced large magnetic change at room temperature and radical-quenched spin glass in a cyanide-bridged Mn^II-Fe^III compound

Dalton Trans. 2023 Nov 7;52(43):15677-15681. doi: 10.1039/d3dt03080f.

Authors

Li-Zhen Cai¹, Xiao-Qing Yu¹, Ming-Sheng Wang¹, Guo-Cong Guo¹

Affiliation

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. gcguo@fjirsm.ac.cn.

PMID: 37888847
DOI: 10.1039/d3dt03080f

Abstract

By the coordination assembly of a redox photoactive functional motif and a cyanide-bridged moiety, a cyanide-bridged Mn^II-Fe^III compound with large photoinduced magnetic change at room-temperature due to photoinduced electron transfer was obtanied. This compound also shows unprecedented radical-quenched spin glass in molecule based magnets.