Defect-Driven Efficient Selective CO2 Hydrogenation with Mo-Based Clusters

Jiajun Zhang; Kai Feng; Zhengwen Li; Bin Yang; Binhang Yan; Kai Hong Luo

doi:10.1021/jacsau.3c00206

Defect-Driven Efficient Selective CO₂ Hydrogenation with Mo-Based Clusters

JACS Au. 2023 Sep 15;3(10):2736-2748. doi: 10.1021/jacsau.3c00206. eCollection 2023 Oct 23.

Authors

Jiajun Zhang^{1

2}, Kai Feng³, Zhengwen Li³, Bin Yang², Binhang Yan³, Kai Hong Luo^{2

4}

Affiliations

¹ National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China.
² Center for Combustion Energy, Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, International Joint Laboratory on Low Carbon Clean Energy Innovation, Tsinghua University, Beijing 100084, China.
³ Department of Chemical Engineering, Tsinghua University, Beijing 100084, China.
⁴ Department of Mechanical Engineering, University College London, Torrington Place, London WC1E 7JE, U.K.

Abstract

Synthetic fuels produced from CO₂ show promise in combating climate change. The reverse water gas shift (RWGS) reaction is the key to opening the CO₂ molecule, and CO serves as a versatile intermediate for creating various hydrocarbons. Mo-based catalysts are of great interest for RWGS reactions featured for their stability and strong metal-oxygen interactions. Our study identified Mo defects as the intrinsic origin of the high activity of cluster Mo₂C for CO₂-selective hydrogenation. Specifically, we found that defected Mo₂C clusters supported on nitrogen-doped graphene exhibited exceptional catalytic performance, attaining a reaction rate of 6.3 g_CO/g_cat/h at 400 °C with over 99% CO selectivity and good stability. Such a catalyst outperformed other Mo-based catalysts and noble metal-based catalysts in terms of facile dissociation of CO₂, highly selective hydrogenation, and nonbarrier liberation of CO. Our study revealed that as a potential descriptor, the atomic magnetism linearly correlates to the liberation capacity of CO, and Mo defects facilitated product desorption by reducing the magnetization of the adsorption site. On the other hand, the defects were effective in neutralizing the negative charges of surface hydrogen, which is crucial for selective hydrogenation. Finally, we have successfully demonstrated that the combination of a carbon support and the carbonization process synergistically serves as a feasible strategy for creating rich Mo defects, and biochar can be a low-cost alternative option for large-scale applications.