Efficient transformation of hydroxylamine from wastewater after supplementation with sodium carbonate or calcium bicarbonate

Ecotoxicol Environ Saf. 2023 Nov 1:266:115603. doi: 10.1016/j.ecoenv.2023.115603. Epub 2023 Oct 17.

Abstract

Hydroxylamine is a highly reactive inorganic nitrogen compound that not only has a toxic effect on microorganisms, but also makes wastewater treatment more difficult, which in turn damages the environment and even endangers human health. This study reported a new method for converting of hydroxylamine by adding sodium carbonate or calcium bicarbonate to the hydroxylamine-polluted wastewater. The conversion efficiency of hydroxylamine was more than 99% in the presence of sodium carbonate or calcium bicarbonate under the reaction conditions of 25 °C, C/N ratio 15, and dissolved oxygen 7.4 mg/L. And its maximal conversion rate can reach 3.49 mg/L/h. This method overcomes various shortcomings of the reported hydroxylamine removal technologies that require a large material dosage and high cost. The technology in this report has many advantages: low cost, 'green' environmental protection, easy market promotion, and high economic benefits.

Keywords: Calcium bicarbonate; Hydroxylamine conversion; Sodium carbonate; Wastewater treatment.

MeSH terms

  • Calcium Carbonate
  • Dietary Supplements
  • Humans
  • Hydroxylamine
  • Hydroxylamines*
  • Nitrogen
  • Wastewater*

Substances

  • sodium carbonate
  • Wastewater
  • calcium bicarbonate
  • Hydroxylamine
  • Hydroxylamines
  • Nitrogen
  • Calcium Carbonate