Photoelectrochemical advanced oxidation processes for simultaneous removal of antibiotics and heavy metal ions in wastewater using 2D-on-2D WS2@CoFe2O4 heteronanostructures

Abstract

The presence of antibiotics in water poses significant threats to both human health and the environment. Addressing this issue requires the effective treatment of medical wastewater. Photoelectrochemical advanced oxidation processes (PEAOPs) are emerging as promising solutions for wastewater treatment. This process utilizes photocatalysts to convert charge carriers into reactive species such as hydroxyl radicals and superoxide ions, which are essential for degrading pollutants in wastewater. However, limitations in charge carrier separation and transport have hindered the efficiency of photoelectrochemical advanced oxidation processes. To overcome these limitations, we designed WS₂@CoFe₂O₄ heterojunctions, optimizing their energy levels to enhance charge transport and separation. This improvement significantly increased the oxidation of antibiotics such as amoxicillin and azithromycin. Multiple reactions occurred at the WS₂@CoFe₂O₄ heterojunctions during photoelectrochemical advanced oxidation processes, leading to the impressive degradation of up to 99% of antibiotics under visible light irradiation at 0.8 V. Urea and H₂O₂ acted as oxidation agents within photoelectrochemical advanced oxidation processes, amplifying the generation of hydroxyl radicals and superoxide ions, further enhancing antibiotic oxidation. Moreover, the WS₂@CoFe₂O₄ photoanode efficiently oxidized toxic antibiotics while converting As(III) into the less harmful As(V). Crucially, recyclability tests confirmed the robustness of the WS₂@CoFe₂O₄ photoanode, ensuring its suitability for prolonged use in photoelectrochemical advanced oxidation processes. Integrating WS₂@CoFe₂O₄ photoanodes into water purification systems can enhance efficiency, reduce energy consumption, and improve economic viability. This technology's scalability and its ability to protect ecosystems while conserving water resources make it a promising solution for addressing the critical issue of antibiotic pollution in water environments.

Keywords: Advanced oxidation process; Antibiotics and heavy metals removal; Environmental chemistry; Photoelectrochemistry; WS(2)@CoFe(2)O(4) heterojunctions; Wastewater treatment.