Characterization and Application of Non-Formaldehyde Binder Based Citric Acid, Maleic Acid, and Molasses Adhesive for Plywood Composite

Polymers (Basel). 2023 Sep 27;15(19):3897. doi: 10.3390/polym15193897.

Abstract

Emissions of formaldehyde from wood-based panels, such as plywood, are gaining increased attention due to their carcinogenic impact on human health and detrimental effects on the environment. Plywood, which is primarily bound with a urea-formaldehyde adhesive, releases formaldehyde during hot pressing and gradually over time. Therefore, this study aims to analyze the impact of non-formaldehyde adhesive types on plywood performance. In addition, plywood performance was assessed by comparing Jabon wood (Anthocephalus cadamba Miq) veneer with other Indonesian wood veneers such as Mempisang (Alphonse spp.) and Mahogany (Swietenia mahagoni). To manufacture a three-layer plywood panel, a two-step manufacturing process was devised. The first step involved the use of Jabon veneers treated with citric acid (CA), maleic acid (MA), and molasses (MO), and another step was carried out for various wood veneers such as Jabon, Mempisang, and Mahogany using CA. The performance of plywood was examined using JAS 233:2003. The performance of plywood bonded with CA was better than that of plywood bonded with MA and MO. The Jabon wood veneer resulted in a lower density of plywood than other wood veneers. The water absorption, thickness swelling, modulus of elasticity, and tensile shear strength of plywood from Jabon wood veneer were similar to those of plywood from Mahogany wood veneer and lower than those of Mempisang wood veneer. The ester linkages of plywood bonded with CA were greater than those of plywood bonded with MA and MO because plywood bonded with CA has better performance than plywood bonded with MA and MO.

Keywords: Indonesian wood; eco-friendly composite; non-formaldehyde adhesive; plywood.