Recovering sensitivity lost through convection in pure shift NMR

Chem Commun (Camb). 2023 Oct 19;59(84):12633-12636. doi: 10.1039/d3cc04112c.

Abstract

Practical pure shift NMR experiments, especially on instruments equipped with cryoprobes, can sometimes give very disappointing results. Here we show for the first time that this is a consequence of signal loss due to sample convection, and demonstrate a simple adjustment to common pure shift NMR experiments that restores the lost signal.