Pushing the limits of PLA by exploring the power of MWCNTs in enhancing thermal, mechanical properties, and weathering resistance

Mohammed M Younus; Hamdy M Naguib; Mohamed Fekry; Moataz A Elsawy

doi:10.1038/s41598-023-43660-3

Pushing the limits of PLA by exploring the power of MWCNTs in enhancing thermal, mechanical properties, and weathering resistance

Sci Rep. 2023 Oct 3;13(1):16588. doi: 10.1038/s41598-023-43660-3.

Authors

Mohammed M Younus¹, Hamdy M Naguib², Mohamed Fekry³, Moataz A Elsawy⁴

Affiliations

¹ Special Processes Lab, Processes Development Division Egyptian Petroleum Research Institute, EPRI, Nasr City, Cairo, 11727, Egypt.
² Department of Petroleum Applications, Egyptian Petroleum Research Institute, Nasr City, Cairo, 11727, Egypt.
³ Polymer Laboratory, Petrochemical Department, Egyptian Petroleum Research Institute, Naser City, Cairo, 11727, Egypt.
⁴ Polymer Laboratory, Petrochemical Department, Egyptian Petroleum Research Institute, Naser City, Cairo, 11727, Egypt. mo3taz_elsawy@yahoo.com.

Abstract

The present study focuses on enhancing the mechanical, thermal, and degradation behavior of polylactic acid (PLA) by adding carbon nanotubes (CNTs) with different concentrations of 0.5, 1, 3, and 5%. The CNTs were prepared using catalytic chemical vapor deposition, and the prepared PLA/CNTs nanocomposite films were characterized using techniques such as FT-IR, Raman spectroscopy, TGA, SEM, and XRD. The distinct diffraction patterns of multi-walled carbon nanotubes (MWCNTs) at 2θ angles of 25.7° and 42.7° were no longer observed in the prepared nanocomposites, indicating uniform dispersion of MWCNTs within the PLA matrix. The presence of MWCNTs enhanced the crystallinity of PLA as the CNT loading increased. Mechanical tests demonstrated that incorporating CNTs positively influenced the elongation at the break while decreasing the ultimate tensile strength of PLA. The PLA-3%CNTs composition exhibited the highest elongation at break (51.8%) but the lowest tensile strength (64 MPa). Moreover, thermal gravimetric analysis confirmed that the prepared nanocomposites exhibited greater thermal stability than pure PLA. Among the nanocomposites, PLA-5% CNTs exhibited the highest thermal stability. Furthermore, the nanocomposites demonstrated reduced surface degradation in accelerated weathering tests, with a more pronounced resilience to UV radiation and moisture-induced deterioration observed in PLA-3% CNTs.