Improving the cycling stability of LiNi0.8Co0.1Mn0.1O2 by boron doping to inhibit Li/Ni mixing

Ziru Hu; Donghong Duan; Haorui Wang; Shoudong Xu; Liang Chen; Ding Zhang

doi:10.1039/d3cc02902f

Improving the cycling stability of LiNi_0.8Co_0.1Mn_0.1O₂ by boron doping to inhibit Li/Ni mixing

Chem Commun (Camb). 2023 Oct 17;59(83):12507-12510. doi: 10.1039/d3cc02902f.

Authors

Ziru Hu¹, Donghong Duan¹, Haorui Wang¹, Shoudong Xu¹, Liang Chen¹, Ding Zhang²

Affiliations

¹ College of Chemical Engineering and Technology, Taiyuan University of Technology, Taiyuan, 030024, Shanxi, China.
² School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan, 430205, Hubei, China. zhangding@wit.edu.cn.

PMID: 37788075
DOI: 10.1039/d3cc02902f

Abstract

Boron doping significantly reduces the Li/Ni cation mixing of LiNi_0.8Co_0.1Mn_0.1O₂, decreases the charge transfer resistance, and improves the reversibility of the H2-H3 phase transition at 4.2 V. Among similar materials, the cathode material with 1.0 mol% boron doping shows excellent cycling performance, with capacity retention of 96% after 200 cycles at 50 °C.