Disclosing the effect of edge defects in carbon-based materials on antibiotic removal remains a great challenge. In this study, carbon-based adsorbents (DC-s) with different degrees of edge defects were synthesized on a large scale via a direct calcination of sodium citrate (SC) and their adsorption performance to antibiotics were explored. The experimental results suggested that the edge defects of DC-s samples were the active sites for the adsorption of tetracycline (TC) and norfloxacin (NOR). The adsorption capacity of the optimal sample DC-900 for TC and NOR was 155.8 and 168.0 mg g-1, respectively. Density functional theory (DFT) calculations further revealed that zigzag edge defects rather than armchair edge defects were crucial to the excellent adsorption performance of DC-s samples for antibiotics, and the natures for the difference in the adsorption performance of the two edge defects for antibiotics were their different electronic structures. In addition, DC-900 also showed stable adsorption efficiency for antibiotics in the interferences, dynamic adsorption, and cycle experiments, suggesting its good environmental application potential. This study provides new insight into clarifying the natures of edge defects with carbon-based adsorbents for high-efficiency removal of antibiotics, which may guide the exploration of cost-effective carbon-based adsorbents.
Keywords: Adsorption; Antibiotics; Carbon-based adsorbents; DFT calculations; Edge defects; NEXAFS measurements.
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