Monitoring 432 potential pesticides in tomatoes produced and commercialized in Souss Massa region-Morocco, using LC-MS/MS and GC-MS/MS

Abstract

In this work, we monitored 432 pesticide residues in 39 tomato samples (cherry tomato) obtained from local markets in Souss Massa region-Morocco. We used a QuEChERS combined with LC-MS/MS and GC-MS/MS, and the method was validated based on SANTE 11312/2021 guideline. The limits of quantification (LOQ) obtained for most of the pesticides analyzed are at the limit with default EU MRLs or well below other EU MRLs. Recoveries (between 70 and 120%) and RSDs (≤20%) are satisfactory for more than 95% of the analytes at spiking level of 0.01 mg/kg and more than 97% at 0.1 mg/kg. The results indicated that 22 out of 39 tomato samples are positives and the most of our samples had levels lower than the maximum residue levels (MRLs) with average concentrations between 0.011 and 0.156 mg/kg. The most found pesticides were azoxystrobin and difenoconazole in tomato (7 samples). Only buprofezin (0.095 mg/kg) was found above the EU MRLs (0.01 mg/kg). Also, banned pesticides namely benalaxyl, spirodiclofen and imidacloprid have been detected. The results of our study confirm the previous findings and gives insights on the occurrence of different pesticides in tomato samples from Souss Massa region-Morocco.

Keywords: Cherry tomato; GC-MS/MS; LC-MS/MS; Morocco; Pesticide residues.