Removal of Silicon from Magnesite by Flotation: Influence of Particle Size and Mechanical Mechanism

Materials (Basel). 2023 Sep 6;16(18):6095. doi: 10.3390/ma16186095.

Abstract

The feasibility of producing high-density sintered magnesia with a one-step sintering method was investigated by utilizing finely ground magnesite as raw materials for direct flotation. The mechanism of flotation desilication of microfine grain magnesite was investigated by combining microstructure and chemical properties. The results showed that dodecylamine (DDA) has a sorting effect on magnesite reverse flotation desilication. Under the premise of 150 mg/L sodium polyacrylate (PAANa) as an inhibitor and 300 mg/L DDA as a collector, the content and recovery rate of MgO can reach 83.91% and 78.78%, respectively. When sodium oleate (NaOL) was used as a collector, the recovery rate of MgO was only 49.22%; therefore, it is unsuitable for magnesite purification. The flotation effect was affected because MgO particles and SiO2 particles agglomerated in the flotation process. The flotation agent cannot work for a single element but works for the mineral agglomerate. While collecting Si elements, the agglomerated MgO was also brought into the froth layer, making flotation impossible.

Keywords: magnesite; mechanism; microfine particle flotation; particle agglomeration.