Non-Local Vectorial Internal Variables and Generalized Guyer-Krumhansl Evolution Equations for the Heat Flux

Entropy (Basel). 2023 Aug 24;25(9):1259. doi: 10.3390/e25091259.

Abstract

In this paper, we ask ourselves how non-local effects affect the description of thermodynamic systems with internal variables. Usually, one assumes that the internal variables are local, but that their evolution equations are non-local, i.e., for instance, that their evolution equations contain non-local differential terms (gradients, Laplacians) or integral terms with memory kernels. In contrast to this typical situation, which has led to substantial progress in several fields, we ask ourselves whether in some cases it would be convenient to start from non-local internal variables with non-local evolution equations. We examine this point by considering three main lengths: the observation scale R defining the elementary volumes used in the description of the system, the mean free path l of the microscopic elements of the fluid (particles, phonons, photons, and molecules), and the overall characteristic size L of the global system. We illustrate these ideas by considering three-dimensional rigid heat conductors within the regime of phonon hydrodynamics in the presence of thermal vortices. In particular, we obtain a generalization of the Guyer-Krumhansl equation, which may be of interest for heat transport in nanosystems or in systems with small-scale inhomogeneities.

Keywords: classical irreversible thermodynamics; continuum thermodynamics; heat transport; internal variables; phonon hydrodynamics.

Grants and funding

D.J. acknowledges the financial support of the University of Messina, by the resolution of the Academic Senate, dated 23/07/2018, Protocol numbers 56199 and 56210, for two months stay in the University, April and June, as a visiting researcher. L.R. acknowledges the financial support of the University of Messina, under FFABR Unime 2019 and FFABR Unime 2022, to visit the Universitat Autònoma de Barcelona during the periods 5–22 May 2021, 19–26 January 2022, 30 April–12 May 2022, 22–27 February 2023.