A synthetic strategy is demonstrated to prepare two distinct trimers of antiferromagnetically coupled {Cr7 Ni} rings, substantially varying the magnetic interactions between the spin centres. The interactions were studied using multi-frequency cw EPR: in a trimer linked via non-covalent H-bonding interactions no measurable interaction between rings was seen, while in a trimer linked via iso-nicotinate groups isotropic and anisotropic exchange interactions of +0.42 and -0.8 GHz, respectively, were observed. The latter are the same as those for a simpler hetero-dimer system, showing how the spin-spin interactions can be built in a predictable and modular manner in these systems.
Keywords: antiferromagnetically coupled; chiral rings; heterometallic rings; multi-spin system; qubit.
© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.