Recent experimental advances in ultrafast science have put different processes occurring on the electronic timescale below a few femtoseconds in focus. In the present theoretical work, we demonstrate how the transformation and propagation of the density matrix in the basis of irreducible spherical tensors can be conveniently used to study sub-few fs spin-flip dynamics in core-excited transition metal compounds. With the help of the Wigner-Eckart theorem, such a transformation separates the essential dynamical information from the geometric factors governed by the angular momentum algebra. We show that an additional reduction can be performed by the physically motivated truncation of the spherical tensor basis. In particular, depending on the degree of coherence, the ultrafast dynamics can be considered semi-quantitative in the notably reduced spherical basis when only the total populations of the basis states of the given spin are of interest. Such truncation should be especially beneficial when the number of high-spin basis states is vast, as it reduces computational costs.
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