Integrating nanomaterials into the polymer matrix is an effective strategy to optimize the performance of polymer-based piezoelectric devices. Nevertheless, the trade-off between the output enhancement and stability maintenance of piezoelectric composites usually leads to an unsatisfied overall performance for the high-strength operation of devices. Here, by setting liquid metal (LM) nanodroplets as the nanofillers in a poly(vinylidene difluoride) (PVDF) matrix, the as-formed liquid-solid/conductive-dielectric interfaces significantly promote the piezoelectric output and the reliability of this piezoelectric composite. A giant performance improvement featured is obtained with, nearly 1000% boosting on the output voltage (as high as 212 V), 270% increment on the piezoelectric coefficient (d33 ∼51.1 pC N-1 ) and long-term reliability on both structure and output (over 36 000 cycles). The design of a novel heterogenous interface with both mechanical matching and electric coupling can be the new orientation for developing high performance piezoelectric composite-based devices.
Keywords: liquid metals; liquid-solid interface; piezoelectric composites; piezoelectric energy harvester.
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