Fabricating s-collidine-derived vinylene-linked covalent organic frameworks for photocatalysis

Zuyi Li; Wengjing Wang; Feng Tao; Wenwen Zhou; Lianke Wang; Zhipeng Yu; Kaixuan Wang; Jie Zhang; Hongping Zhou

doi:10.1039/d3cc03446a

Fabricating s-collidine-derived vinylene-linked covalent organic frameworks for photocatalysis

Chem Commun (Camb). 2023 Sep 28;59(78):11728-11731. doi: 10.1039/d3cc03446a.

Authors

Zuyi Li¹, Wengjing Wang¹, Feng Tao¹, Wenwen Zhou¹, Lianke Wang¹, Zhipeng Yu¹, Kaixuan Wang¹, Jie Zhang¹, Hongping Zhou¹

Affiliation

¹ Institute of Material Science and Information Technology, College of Chemistry and Chemical Engineering Anhui University and Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education, Hefei, 230601, P. R. China. zhangjiechem@hotmail.com.

PMID: 37702593
DOI: 10.1039/d3cc03446a

Abstract

Research into vinyl-linked covalent organic frameworks (COFs) has grown significantly in recent years due to various attractive properties. Herein, we design and synthesize two highly crystalline and stable 2,4,6-collidine-derived vinylene-linked 2D COFs. Both COFs can act as efficient photocatalysts to facilitate visible-light-driven aerobic oxidation. The TM-TBT-COF was observed to exhibit superior activity and recyclability owing to its excellent semiconducting properties.