Coupling flow and electric fields to simulate migration and remediation of uranium in groundwater remediated by electroosmosis and a permeable reactive bio-barrier

Fuxin Zheng; Yuanzheng Zhai; Weifeng Yue; Yanguo Teng

doi:10.1016/j.jenvman.2023.118947

Coupling flow and electric fields to simulate migration and remediation of uranium in groundwater remediated by electroosmosis and a permeable reactive bio-barrier

J Environ Manage. 2023 Nov 15:346:118947. doi: 10.1016/j.jenvman.2023.118947. Epub 2023 Sep 10.

Authors

Fuxin Zheng¹, Yuanzheng Zhai², Weifeng Yue¹, Yanguo Teng¹

Affiliations

¹ Engineering Research Center for Groundwater Pollution Control and Remediation of Ministry of Education of China, College of Water Sciences, Beijing Normal University, Beijing, 100875, China.
² Engineering Research Center for Groundwater Pollution Control and Remediation of Ministry of Education of China, College of Water Sciences, Beijing Normal University, Beijing, 100875, China. Electronic address: zyz@bnu.edu.cn.

PMID: 37699289
DOI: 10.1016/j.jenvman.2023.118947

Abstract

Combined remediation technologies are increasingly being considered to uranium contaminated groundwater, such as the joint utilize of permeable reactive bio-barrier (Bio-PRB) and electrokinetic remediation (EKR). While the assessment of uranium plume evolution in the combined remediation system (CRS) have often been impeded by insufficient understanding of multi-physical field superposition. Therefore, advanced knowledge in multi-physical field coupling in groundwater flow will be crucial to the practical application of these techniques. A two-dimensional multi-physical field coupling model was constructed for predicting the uranium degradation in CRS. The study demonstrates that the coupling model is able to predict the uranium plume evolution and rapidly evaluate the performance of CRS components. The results show that field electric direction and flow field strength are the key factors that affect the retardation and remediation performance of CRS. The reverse electric field direction significantly affected the contact reaction time of uranium in the system. The uranium residence time in the reverse electric field was 3.8 d, which was significantly greater than the original electric field (2.0 d). Depending on the voltage, the reverse electric field direction was 16%-36% more efficient than the original direction. The strength of the flow field was about two orders of magnitude higher than that of the electric field, so the groundwater flow rate dominated remediation efficiency. Reducing the flow rate by 1/2 could improve the performance of the system by approximately 66%. In addition, the coupling model can be utilized to design standard CRS for real site of uranium contaminated groundwater. To meet the optimal performance, the direction of the electric field should be set opposite to the flow field. This work has successfully used a coupling model to predict uranium contaminant-plume evolution in CRS and estimate the performance of each component.

Keywords: COMSOL multiphysics; Electrokinetic remediation; FEFLOW; Numerical model coupling; Permeable reactive barrier; Uranium remediation.