Effects of chemical aging on carbonaceous materials: Stability of water-dispersible colloids and their influence on the aggregation of natural-soil colloid

Laís G Fregolente; Maria T Rodrigues; Naiara C Oliveira; Bruno Sousa Araújo; Ícaro V Nascimento; Antonio G Souza Filho; Amauri J Paula; Mirian C G Costa; Jaedson C A Mota; Odair P Ferreira

doi:10.1016/j.scitotenv.2023.166835

Effects of chemical aging on carbonaceous materials: Stability of water-dispersible colloids and their influence on the aggregation of natural-soil colloid

Sci Total Environ. 2023 Dec 10:903:166835. doi: 10.1016/j.scitotenv.2023.166835. Epub 2023 Sep 9.

Affiliations

¹ Physics Department, Universidade Federal do Ceará, Fortaleza, Ceará State postcode 60455-900, Brazil. Electronic address: laisfregolente@fisica.ufc.br.
² Physics Department, Universidade Federal do Ceará, Fortaleza, Ceará State postcode 60455-900, Brazil.
³ Soil Science Department, Universidade Federal do Ceará, Fortaleza, Ceará State postcode 60455-900, Brazil.
⁴ Physics Department, Universidade Federal do Ceará, Fortaleza, Ceará State postcode 60455-900, Brazil; Ilum School of Science, Centro Nacional de Pesquisa em Energia e Materiais - CNPEM, Campinas, São Paulo State, Brazil.
⁵ Physics Department, Universidade Federal do Ceará, Fortaleza, Ceará State postcode 60455-900, Brazil; Laboratório de Materiais Funcionais Avançados (LaMFA), Chemistry Department, Universidade Estadual de Londrina, Londrina, Paraná State postcode 86057-970, Brazil.

PMID: 37678531
DOI: 10.1016/j.scitotenv.2023.166835

Abstract

Although hydrochar and biochar have been used as soil conditioners, there is not a clear understanding of how their properties changes due to aging impacts their colloidal particles behavior on the soil system. From this premise, we produced hydrochar and biochar from the same feedstock (cashew bagasse) and aged with different chemical methods: (i) using hydrogen peroxide, (ii) a mixture of nitric and sulfuric acids, and (iii) hot water. It was analyzed the effects of aging on the stability of the carbonaceous materials (CMs) colloids in aqueous medium with different ionic strength (single systems), as well as the stability of the natural-soil colloid when interacting with biochar and hydrochar colloids (binary systems). A chemical composition (C, H, N, and O content) change in CMs due to the chemically induced aging was observed along with minor structural modifications. Chemical aging could increase the amount of oxygen functional groups for both biochar and hydrochar, though in a different level depending on the methodology applied. In this sense, hydrochar was more susceptive to chemical oxidation than biochar. The effectiveness of chemical aging treatments for biochar increased in the order of water < acid < hydrogen peroxide, whereas for hydrochar the order was water < hydrogen peroxide < acid. While the increase in surface oxidation improved the biochar colloidal stability in water medium at different ionic strengths (single systems), the stability and critical coagulation concentration (CCC) slightly changed for hydrochar. Natural-soil clay (NSC) interactions with oxidized carbonaceous material colloids (binary systems) enhanced NSC stability, which is less likely to aggregate. Therefore, the aging of carbonaceous materials modifies the interaction and dynamics of soil small particles, requiring far more attention to the environmental risks due to their application over time.

Keywords: Aggregation; Biochar; Hydrochar; Hydrothermal carbonization; Oxidation; Pyrolysis.