Supramolecular organic frameworks (SOFs) are a class of three-dimensional, potentially porous materials obtained by the self-assembly of organic building blocks held together by weak interactions such as hydrogen bonds, halogen bonds, π⋅⋅⋅π stacking and dispersion forces. SOFs are being extensively studied for their potential applications in gas storage and separation, catalysis, guest encapsulation and sensing. The supramolecular forces that guide their self-assembly endow them with an attractive combination of crystallinity and flexibility, providing intelligent dynamic materials that can respond to external stimuli in a reversible way. The present review article will focus on SOFs showing dynamic behaviour when exposed to different stimuli, highlighting fundamental aspects such as the combination of tectons and supramolecular interactions involved in the framework formation, structure-property relationship and their potential applications.
Keywords: crystal engineering; noncovalent interactions; stimuli-responsive materials; structure-activity relationships; supramolecular organic frameworks.
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