The first evidence of microplastic occurrence in mine water: The largest black coal mining area in the Czech Republic

Abstract

Climate change is creating new challenges for water supply worldwide, making the search for new sources of water vital. As mine water could serve as a potential source, this study investigated the presence of microplastics in water from terminated deep mines in the largest coal basin in the Czech Republic, as well as in water from nearby shallow wells. The particles found were analyzed for size, polymer composition, color and morphology using the ImageJ tool, infrared spectroscopy with Fourier transform (FTIR) and an optical stereomicroscope with a digital camera. Microplastics were detected in all tested sites. Their range accounted for 2.5-17.5 items/L for mine water samples and 2.5-20 items/L for well samples, with fibers being the dominant type. The average width of particles from mine water and wells amounted to 58 µm; 71 µm, length to 655 µm; 501 µm and area to 22,067 µm2; 28,613 µm2, respectively. Blue color was prevalent, among materials, in both cases, plastic coated paper was found dominant to Polyethylene terephthalate (PET), Polyester (PES), Tetrafluoroethylene-perfluoro (Propyl Vinyl Ether) - Copolymer (TFE-PPVE), and polypropylene (PP). The research provides the first evidence of microplastics' presence in underground waters from deep mines and shallow wells in the same area. The data suggest that it is almost impossible to find underground water sources free of microplastic contamination. In this context, atmospheric contamination from mine ventilation and infiltration through terminated mines were identified as potential sources, while infiltration through soil and rock formations is unlikely given the geological composition. The results of this study can serve as a relevant basis for further research on microplastics in mine waters. Additionally, the conclusions can advance the development in remediation technologies of microplastics from deep underground waters and their implementation in practice, particularly in light of upcoming legislation.

Keywords: Characterization; FTIR; Groundwater; Microplastics; Mining; Pollution.