Facile synthesis of bimetallic ACF/CC@FeOCl-Cu composite cathode for efficient degradation of sulfamethoxazole at neutral pH by a flow-through heterogeneous electro-Fenton process

Abstract

Flow-through heterogeneous electro-Fenton (FHEF) process shows a broad prospect for refractory organic pollutants removal. However, maintaining a long-term service life of higher catalytic cathode is crucial for the development of cathode materials, especially for iron-functionalized cathode operated under harsh conditions. In this study, a novel bimetallic CC@FeOCl-Cu composite was synthesized through one-step calcination, coupled with a series of microstructure characterization methodology, including XRD, SEM-EDS, XPS, and FTIR. The superior catalytic activity of CC@FeOCl-Cu could be ascribed to Fe-Cu synergy and better dispersion of FeOCl nanosheets. With the optimal Cu:Fe ratio of 1:60, the bifunctional ACF/CC@FeOCl-Cu cathode was employed in FHEF process, exhibiting an outstanding performance for sulfamethoxazole (SMX) removal over a wide pH range (3.0-9.0). Comparison of experimental results indicated that the ACF/CC@FeOCl-Cu-FHEF process showed higher performance than ACF/CC@FeOCl-FHEF and homogeneous EF processes. The average SMX removal efficiency was 98% and TOC removal efficiency was more than 57% even after 10 cycles. Radical quenching experiments and electron spin resonance test confirmed that ^•OH was the primary active species. More ^•OH was generated in the ACF/CC@FeOCl-Cu-FHEF process because the doping of Cu could enhance catalytic activity of cathode. In addition, the satisfactory performance could be observed in the ACF/CC@FeOCl-Cu-FHEF process for the treatment of real landfill leachate, indicating its potential for practical application in wastewater treatment.

Keywords: ACF/CC@FeOCl–Cu cathode; Flow-through heterogeneous electro-Fenton; Hydroxyl radical; Sulfamethoxazole degradation.