Superplastic Nanomolding of Aluminum Waveguides for Subwavelength Light Routing, Splitting, and Encryption

ACS Nano. 2023 Sep 12;17(17):17342-17349. doi: 10.1021/acsnano.3c05358. Epub 2023 Aug 28.

Abstract

Plasmonic nanowires (NWs) due to their polarization-dependent optics and enhanced light-matter interactions have presented vibrant capabilities in functional nanophotonic devices. However, current demonstrations have largely been based on chemically synthesized Ag NWs, which are extremely unstable and poorly functional. Here we show single-crystalline Al NWs can be fabricated by a superplastic nanomolding (SPNM) technique on a centimeter scale, which are earth-abundant and highly stable. They present robust properties of multimode waveguiding with long-term stability, high efficiency of beam splitting in response to the polarization, and durable thermal optical modulation, which can be readily applied as nanophotonic routers, splitters, and information encryptors. Moreover, this SNPM technique is extendable to other metals, which are highly exploitable for functional nanophotonic devices and integrated optical chips.

Keywords: modulation; nanomolding; nanowires; optical information; surface plasmons.