Enhanced Oxygen Storage Capacity of Porous CeO2 by Rare Earth Doping

Yaohui Xu; Liangjuan Gao; Quanhui Hou; Pingkeng Wu; Yunxuan Zhou; Zhao Ding

doi:10.3390/molecules28166005

Enhanced Oxygen Storage Capacity of Porous CeO₂ by Rare Earth Doping

Molecules. 2023 Aug 10;28(16):6005. doi: 10.3390/molecules28166005.

Authors

Yaohui Xu^{1

2}, Liangjuan Gao³, Quanhui Hou⁴, Pingkeng Wu⁵, Yunxuan Zhou⁶, Zhao Ding⁶

Affiliations

¹ Laboratory for Functional Materials, School of New Energy Materials and Chemistry, Leshan Normal University, Leshan 614000, China.
² Leshan West Silicon Materials Photovoltaic and New Energy Industry Technology Research Institute, Leshan 614000, China.
³ College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China.
⁴ School of Automotive Engineering, Yancheng Institute of Technology, Yancheng 224051, China.
⁵ Department of Chemical Engineering, Illinois Institute of Technology, Chicago, IL 60616, USA.
⁶ College of Materials Science and Engineering, National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing 400044, China.

Abstract

CeO₂ is an important rare earth (RE) oxide and has served as a typical oxygen storage material in practical applications. In the present study, the oxygen storage capacity (OSC) of CeO₂ was enhanced by doping with other rare earth ions (RE, RE = Yb, Y, Sm and La). A series of Undoped and RE-doped CeO₂ with different doping levels were synthesized using a solvothermal method following a subsequent calcination process, in which just Ce(NO₃)₃∙6H₂O, RE(NO₃)₃∙nH₂O, ethylene glycol and water were used as raw materials. Surprisingly, the Undoped CeO₂ was proved to be a porous material with a multilayered special morphology without any additional templates in this work. The lattice parameters of CeO₂ were refined by the least-squares method with highly pure NaCl as the internal standard for peak position calibrations, and the solubility limits of RE ions into CeO₂ were determined; the amounts of reducible-reoxidizable Ceⁿ⁺ ions were estimated by fitting the Ce 3d core-levels XPS spectra; the non-stoichiometric oxygen vacancy (V_O) defects of CeO₂ were analyzed qualitatively and quantitatively by O 1s XPS fitting and Raman scattering; and the OSC was quantified by the amount of H₂ consumption per gram of CeO₂ based on hydrogen temperature programmed reduction (H₂-TPR) measurements. The maximum [OSC] of CeO₂ appeared at 5 mol.% Yb-, 4 mol.% Y-, 4 mol.% Sm- and 7 mol.% La-doping with the values of 0.444, 0.387, 0.352 and 0.380 mmol H₂/g by an increase of 93.04, 68.26, 53.04 and 65.22%. Moreover, the dominant factor for promoting the OSC of RE-doped CeO₂ was analyzed.

Keywords: CeO2; doping; oxygen storage capacity; porous; rare earth; solvothermal.

Abstract

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