Bioactive Polyoxymethylene Composites: Mechanical and Antibacterial Characterization

Materials (Basel). 2023 Aug 21;16(16):5718. doi: 10.3390/ma16165718.

Abstract

The aim of this study is to analyze the strength and antibacterial properties of composites based on structural polyoxymethylene. The base material was modified with the most used antibacterial additives, such as silver nanoparticles, copper oxide, zinc oxide, and titanium oxide. Basic strength and low-cycle fatigue tests were conducted to determine the dissipation energy of the material. The composites were also tested for antibacterial properties against two strains of bacteria: Escherichia coli ATCC 8739 and Staphylococcus aureus ATCC 6538. Strength properties showed no significant changes in the mechanical behavior of the tested composites against the matrix material. The best antibacterial additive was the addition of titanium oxide nanoparticles, providing 100% efficacy against Escherichia coli and almost 100% biocidal efficacy against Staphylococcus aureus. The other antibacterial additives showed biocidal efficacy of about 30-40% against the unmodified material. The added value of the work is the consistency in the methodology of testing materials modified with antibacterial additives, as well as the same compactness of the introduced additives. This study makes it clear which of the introduced additives has the highest biocidal activity.

Keywords: copper oxide; polyoxymethylene; silver nanoparticles; titanium oxide; zinc oxide.