Properties of Self-Compacting Concrete Produced with Optimized Volumes of Calcined Clay and Rice Husk Ash-Emphasis on Rheology, Flowability Retention and Durability

Materials (Basel). 2023 Aug 8;16(16):5513. doi: 10.3390/ma16165513.

Abstract

The durability of concrete requires a dense microstructure which can be achieved by using self-compacting concrete (SCC). Both calcined clay (CC) and rice husk ash (RHA) are promising supplementary cementitious materials (SCMs) that can partially replace cement, but their use in SCC is critical due to their higher water demand (WD) and specific surface area (SSA) compared to cement. The effect of partial substitution of cement at 20 vol-% with binary and ternary blends of CC and RHA on flowability retention and durability of SCC was investigated. The empirical method of SCC design was adopted considering the physical properties of both CC and RHA. The deformability of the SCC was evaluated using the slump flow and J-ring tests. The T500 time and the V-funnel test were used to assess the viscosity of the SCC. The flowability retention was monitored by the plunger method, and flow resistance was determined based on the rheological measurements of SCC. The evolution of the hydrate phases of the binder in SCC was determined by thermogravimetric analysis, while the durability was evaluated by a rapid chloride migration test. Cement partial replacement with 20 vol-% CC has no significant effect on fresh SCC, flowability retention, compressive strength and durability properties. On the other hand, 20 vol-% RHA requires a higher dosage of SP to achieve self-compactability and increase the viscosity of SCC. Its flowability retention is only up to 30 min after mixing and exhibited higher flow resistance. It consumes more calcium hydroxide (CH) and improves the compressive strength and chloride resistance of SCC. The ternary blending with CC and RHA yielded better fresh SCC properties compared to the binary blend with RHA, while an improved chloride penetration resistance could be achieved compared to the binary CC blend.

Keywords: calcined clay; durability; flow resistance; flowability retention; reactivity; rheology; rice husk ash; self-compacting concrete.