Immobilization of cadmium in paddy soil using a novel active silicon-potassium amendment: a field experimental study

Abstract

The rapid development of industrialization and agriculture has led to extensive environmental issues worldwide such as cadmium (Cd) pollution of paddy soils, posing a potential threat to environmental safety and food health. Therefore, there is an urgent need to reduce the Cd contents in paddy soils. In this study, a newly active silicon-potassium amendment was first prepared from potassium hydroxide-assisted potassium feldspar at a low temperature, and then was used to remediate a contaminated paddy soil by Cd over a long period. The obtained results demonstrated the effectiveness of the applied active silicon-potassium in promoting rice growth in the experimental field. In addition, soil pH values increased to 6.89-7.03, thus decreasing the bioavailability of Cd bioavailability by 8.61-13.7%. The soil enzyme activities and available nutrients (Si, Ca, Mg, N, and P) were also significantly increased. In particular, the Cd contents in the rice grains decreased from 0.279 to 0.179-0.194 mg/kg following the application of the active silicon-potassium amendment, reaching the food crop standard level of China (< 0.2 mg/kg). The detailed remediation mechanisms of the Cd-contaminated paddy soil involved several processes, including ion exchange, ligand complexation, electrostatic attraction, and precipitation. Overall, the active silicon-potassium material is a promising amendment for achieving effective control of Cd-contaminated paddy soils.

Keywords: Active silicon-potassium; Cadmium; Potassium feldspar; Soil remediation.