Multiply engaged molecular gears composed of a cerium(IV) double-decker of a triptycene-functionalized porphyrin

Toshio Nishino; Masafumi Fukumura; Shohei Katao; Kazuma Yasuhara; Gwénaël Rapenne

doi:10.1039/d3dt02443a

Multiply engaged molecular gears composed of a cerium(IV) double-decker of a triptycene-functionalized porphyrin

Dalton Trans. 2023 Aug 29;52(34):11797-11801. doi: 10.1039/d3dt02443a.

Authors

Toshio Nishino¹, Masafumi Fukumura¹, Shohei Katao¹, Kazuma Yasuhara^{1

2}, Gwénaël Rapenne^{1

3}

Affiliations

¹ Division of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan.
² Centre of Digital Green-Inovation, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara, Japan.
³ CEMES, Université de Toulouse, CNRS, 29, rue Jeanne Marvig, 31055 Toulouse, France. rapenne@cemes.fr.

PMID: 37593796
DOI: 10.1039/d3dt02443a

Abstract

Intramolecular gearing motions are studied in a cerium(IV) double-decker of triptycene-functionalised porphyrins using single crystal X-ray analysis and variable temperature ¹H-NMR.