Removal performance and mechanisms of aqueous Cr (VI) by biochar derived from waste hazelnut shell

Abstract

Cr (VI) is still of great concern due to its high toxicity, solubility, and mobility. The transformation of waste biomass to biochar is favorable for sustainable development. Hazelnut shell, an agriculture waste, was utilized as precursor to prepare biochar at 700 °C and firstly conducted for Cr (VI) removal. Nearly all 50 mg L^-1 of Cr (VI) was removed from aqueous media in 180 min under the optimal conditions. The best compliance with pseudo-second-order kinetic model (R² = 0.999) and Langmuir isotherm model (R² = 0.999) indicated Cr (VI) removal was a monolayer chemisorption process. The hazelnut shell biochar exhibited superior performance on Cr (VI) removal at low pH (2.0) and Cr (VI) concentrations (≤ 50 mg L^-1). Various techniques illustrated that the predominant mechanism of Cr (VI) removal by hazelnut shell biochar involved electrostatic attraction, reduction, and complexation. This study provides a promising low-cost alternative for Cr (VI) elimination from acidic wastewater and groundwater after extraction following by pH adjustment to 2.0.

Keywords: Biochar; Hazelnut shell; Hexavalent chromium; Removal mechanisms; X-ray photoelectron spectroscopy.