Achieving above 24% efficiency with non-toxic CsSnI3 perovskite solar cells by harnessing the potential of the absorber and charge transport layers

M Khalid Hossain; M Shihab Uddin; G F Ishraque Toki; Mustafa K A Mohammed; Rahul Pandey; Jaya Madan; Md Ferdous Rahman; Md Rasidul Islam; Sagar Bhattarai; H Bencherif; D P Samajdar; Mongi Amami; D K Dwivedi

doi:10.1039/d3ra02910g

Achieving above 24% efficiency with non-toxic CsSnI₃ perovskite solar cells by harnessing the potential of the absorber and charge transport layers

RSC Adv. 2023 Aug 4;13(34):23514-23537. doi: 10.1039/d3ra02910g.

Authors

Affiliations

¹ Institute of Electronics, Atomic Energy Research Establishment, Bangladesh Atomic Energy Commission Dhaka 1349 Bangladesh khalid.baec@gmail.com khalid@kyudai.jp.
² Department of Electrical and Electronic Engineering, Islamic University Kushtia 7000 Bangladesh.
³ College of Materials Science and Engineering, Donghua University Shanghai 201620 China.
⁴ University of Warith Al-Anbiyaa 56001 Karbala Iraq.
⁵ VLSI Centre of Excellence, Chitkara University Institute of Engineering and Technology, Chitkara University Punjab 140401 India jaya.madan@chitkara.edu.in.
⁶ Advanced Energy Materials and Solar Cell Research Laboratory, Department of Electrical and Electronic Engineering, Begum Rokeya University Rangpur 5400 Bangladesh.
⁷ Department of Electrical and Electronic Engineering, Bangamata Sheikh Fojilatunnesa Mujib Science & Technology University Jamalpur 2012 Bangladesh.
⁸ Technology Innovation and Development Foundation, Indian Institute of Technology Guwahati Guwahati 781039 Assam India.
⁹ LEREESI, Higher National School of Renewable Energies, Environment and Sustainable Development Batna 05078 Algeria bencherif.hichem@hns-re2sd.dz.
¹⁰ Dept. of ECE, Indian Institute of Information Technology, Design & Manufacturing Madhya Pradesh 482005 India.
¹¹ Department of Chemistry, College of Sciences, King Khalid University P.O. Box 9004 Abha Saudi Arabia.
¹² Department of Physics and Material Science, Madan Mohan Malaviya University of Technology Gorakhpur 273010 U.P. India.

Abstract

Lead toxicity is a barrier to the widespread commercial manufacture of lead halide perovskites and their use in solar photovoltaic (PV) devices. Eco-friendly lead-free perovskite solar cells (PSCs) have been developed using certain unique non- or low-toxic perovskite materials. In this context, Sn-based perovskites have been identified as promising substitutes for Pb-based perovskites due to their similar characteristics. However, Sn-based perovskites suffer from chemical instability, which affects their performance in PSCs. This study employs theoretical simulations to identify ways to improve the efficiency of Sn-based PSCs. The simulations were conducted using the SCAPS-1D software, and a lead-free, non-toxic, and inorganic perovskite absorber layer (PAL), i.e. CsSnI₃ was used in the PSC design. The properties of the hole transport layer (HTL) and electron transport layer (ETL) were tuned to optimize the performance of the device. Apart from this, seven different combinations of HTLs were studied, and the best-performing combination was found to be ITO/PCBM/CsSnI₃/CFTS/Se, which achieved a power conversion efficiency (PCE) of 24.73%, an open-circuit voltage (V_OC) of 0.872 V, a short-circuit current density (J_SC) of 33.99 mA cm^-2 and a fill factor (FF) of 83.46%. The second highest PCE of 18.41% was achieved by the ITO/PCBM/CsSnI₃/CuSCN/Se structure. In addition to optimizing the structure of the PSC, this study also analyzes the current density-voltage (J-V) along with quantum efficiency (QE), as well as the impact of series resistance, shunt resistance, and working temperature, on PV performance. The results demonstrate the potential of the optimized structure identified in this study to enhance the standard PCE of PSCs. Overall, this study provides important insights into the development of lead-free absorber materials and highlights the potential of using CsSnI₃ as the PAL in PSCs. The optimized structure identified in this study can be used as a base for further research to improve the efficiency of Sn-based PSCs.