This paper presents facile photoresponsive actuators comprising ferrocene as a guest chromophore and poly(butyl methacrylate) (PBMA) as a host matrix. The ferrocene-doped PBMA film exhibits mechanical expansion and contraction when a 445 nm laser is turned on and off, respectively. The photoresponsive film is attached by a commercially available acetylcellulose adhesive tape, which exhibits a bending motion that is controlled by turning the laser on and off. Thereafter, the double-layer film is employed to fabricate a table-shaped lifting machine (0.7 mg) that lifts a 10.5 mg object up and down by turning the laser on and off, respectively, and the mechanical force offered by the double-layer film is recorded. Additionally, the film is coated with gold and applied to an electric circuit that serves as a reversible photoresponsive switch. This film preparation technique is applied to other chromophores (e.g., Coumarin 343, Rhodamine 6G, Sudan Blue II, and Solvent Green 3) to independently control the motions of the films with 445, 520, and 655 nm lasers. The ferrocene-containing films also exhibit photoinduced healing from mechanical damage. Finally, the photoirradiation-accompanied morphological changes in the film are observed via small-angle X-ray scattering.
Keywords: bending; ferrocene; healing; photoresponsive actuators; poly(butyl methacrylate).