Stable food grade wax/attapulgite superhydrophobic coatings for anti-adhesion of liquid foods

J Colloid Interface Sci. 2023 Nov 15;650(Pt A):865-874. doi: 10.1016/j.jcis.2023.07.042. Epub 2023 Jul 9.

Abstract

Adhesion of liquid foods on their packaging materials has caused significant food wastes and environment pollution, which has attracted great attention. Food grade superhydrophobic coatings are very promising to solve the issue but suffer from low mechanical stability and complex preparation methods. Herein, a food grade superhydrophobic coating for anti-adhesion of liquid foods was prepared by combining edible paraffin wax, polydimethylsiloxane-modified attapulgite natural nanorods and a food grade silicone adhesive. The concentration of polydimethylsiloxane-modified attapulgite, ultrasonication time and the volume ratio of the paraffin wax/attapulgite suspension to the silicone adhesive solution have great influences on wettability and morphology of the coatings. The coatings exhibit good static and dynamic superhydrophobicity due to their hierarchical micro-/nanostructure and low surface energy of the polydimethylsiloxane-modified attapulgite and paraffin wax. Moreover, the coatings exhibit good mechanical and chemical stability. The coatings are also highly repellent towards various liquid foods including the hot ones. Furthermore, the coatings are applicable onto various frequently used flexible and hard food packing materials including polypropylene, polyethylene terephthalate, aluminium alloy and paper, etc. Thus, the superhydrophobic coatings have great application potential in the food packing industry for anti-adhesion of liquid foods.

Keywords: Anti-adhesive; Attapulgite; Food packing; Paraffin wax; Superhydrophobicity.

MeSH terms

  • Dimethylpolysiloxanes* / chemistry
  • Hydrophobic and Hydrophilic Interactions
  • Paraffin*
  • Silicones

Substances

  • attapulgite
  • Paraffin
  • Dimethylpolysiloxanes
  • Silicones