Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar

Materials (Basel). 2023 Jun 30;16(13):4730. doi: 10.3390/ma16134730.

Abstract

The purpose of this study was to recycle red mud, an industrial byproduct that generates 300,000 tons per year, into the construction industry. Red mud was prepared as a liquid, neutralized with sulfuric acid, and replaced with cement mortar. The properties of liquefied red mud (LRM) neutralized with sulfuric acid (LRM + S) were investigated as well as its effect on cement mortar's mechanical and hydration characteristics. The pH of LRM + S stabilized at 7.6; its SO3 content was ~4.19% higher than that of LRM. Sulfites were contributed by calcium and sodium sulfate. The flows and setting times of the mortars containing LRM and LRM + S decreased as the substitution rate increased. The compressive strength of mortar that replaced 5% of cement with LRM + S was similar to that of the plain cement mortar. Scanning electron microscopy and X-ray diffraction revealed that the hydration products of LRM + S-containing cement mortar were similar to those of the plain cement mortar. Thus, LRM + S can be used as a cement substitute.

Keywords: SEM; X-ray diffraction; cement mortars; liquefied red mud; neutralized red mud; recycling; red mud.

Grants and funding

This work is supported by the Korea Agency for Infrastructure Technology Advancement (KAIA) grant funded by the Ministry of Land, Infrastructure and Transport (Grant 22TBIP-C160747-02). This work also was supported by the Technology development Program (S3303468) funded by the Ministry of SMEs and Startups (MSS, Korea).