Synthesis and characterization of visible-light-driven novel CuTa2O6 as a promising practical photocatalyst

Abstract

In this work, the novel CuTa₂O₆ phase was successfully synthesized by the hydrothermal and followed by the calcination process. The X-ray diffraction pattern confirms the formation of different phases. At a low temperature, CuTa₂O₆ exhibits the orthorhombic phase, whereas, at a higher temperature, it underwent a phase transition to a cubic crystal structure. X-ray photoelectron spectroscopic results suggest the presence of all the elements (Cu, Ta, and O). The optical studies were carried out using a UV-Vis DRS spectrophotometer. FESEM images confirm the spherical-shaped particles for the sample annealed at a high temperature. The local atomic and electronic structures around Cu and the contribution of the Cu oxidation state in the CuTa₂O₆ system were determined by X-ray absorption spectroscopy. To investigate the effective usage of CuTa₂O₆ in treating wastewater, its photocatalytic activity was investigated by evaluating its use in the photodegradation of MO dye under visible light irradiation. Moreover, the prepared CuTa₂O₆ photocatalyst exhibits significant photocatalytic activity in the degradation of MO dye and shows excellent stability; it is therefore a promising material for potential use in a practical photocatalyst. The CuTa₂O₆ photocatalyst suggests an alternative avenue of research into effective photo-catalysts for solar hydrogen water splitting.

Keywords: X-ray absorption spectroscopy (XAS); dye degradation; phase transition; photocatalytic activity; visible light irradiation.