In recent decades, the efficient utilization of solar energy through heterogeneous photocatalytic chemical transformation has attracted much attention. As emerging metal-free, pure organic and heterogeneous photocatalysts, π-conjugated polymers (CPs) have been used in visible-light-driven chemical transformations due to their stability, high specific surface area, metal-free nature, and high structural designability. In this review, we summarize the synthesis protocols and design strategies for efficient CP-based photocatalysts based on the photocatalytic mechanisms. Then we highlight the key progress in light-driven chemical transformation using CPs developed by our group. Finally, we present the outlook and possible challenges for future progress of the field.