Fabrication of a patterned hydrogen-bonded organic framework (HOF) films on a large scale is an extreme challenge. In this work, a large area HOF film (30 × 30 cm2 ) is prepared via an efficient and low-cost electrostatic spray deposition (ESD) approach on the un-modified conductive substrates directly. Combining the ESD with a template method, variously patterned HOF films can be easily produced, including deer- and horse-shaped films. The obtained films exhibit excellent electrochromic performance with multicolor change from yellow to green and violet, and two-band regulation at 550 and 830 nm. Benefiting from the inherently present channels of HOF materials and the additional film porosity created by ESD, the PFC-1 film could quickly change color (within 10 s). Furthermore, the large-area patterned EC device is constructed based on the above film to prove practical potential application. The presented ESD method can be extended to other HOF materials; thus, this work paves a feasible path for constructing large-area patterned HOF films for practical optoelectronic applications.
Keywords: devices; electrochromism; electrostatic spray deposition; hydrogen-bonded organic frameworks; large-area patterned films.
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