White-light emission from a single organic molecule, known as a single white-light emitter, is a rare phenomenon and desirable property for a class of materials with potential future applications in white lighting. Since N-aryl-naphthalimides (NANs) have been shown to follow excited state behavior and unique dual or panchromatic emission through a substituent pattern prescribed via a seesaw photophysical model, this study investigates the substituent effects on the fluorescence emission of structurally related N-aryl-phenanthridinones (NAPs) dyes. Following a similar placement prescription of an electron-releasing group (ERG) and electron-withdrawing group (EWG) at the phenanthridinone core and N-aryl moiety, we discovered from time-dependent density functional theory (TD-DFT) results that NAPs show a substitution pattern opposite to NANs in order to promote S2 and higher excited states. Interestingly, 2-methoxy-5-[4-nitro-3(trifluoromethyl)phenyl]phenanthridin-6(5H)-one 6e displayed a pronounced dual and panchromatic fluorescence dye depending on the solvent. For the six dyes included in the study, full spectral information in a variety of solvents, as well as fluorescence quantum yield and lifetime are reported. TD-DFT calculations support the predicted optical behavior via mixing of S2 and S6 excited states via anti-Kasha type of emission behavior.