Trace Ammonia Equilibrium Pressure of Zirconium Phosphate in Moisture

Masakuni Yamaguchi; Tomoyuki Ichikawa; Yoshitsugu Kojima; Hiroki Miyaoka

doi:10.1021/acsomega.3c02354

Trace Ammonia Equilibrium Pressure of Zirconium Phosphate in Moisture

ACS Omega. 2023 Jun 14;8(25):23051-23055. doi: 10.1021/acsomega.3c02354. eCollection 2023 Jun 27.

Authors

Masakuni Yamaguchi¹, Tomoyuki Ichikawa², Yoshitsugu Kojima¹, Hiroki Miyaoka¹

Affiliations

¹ Natural Science Center for Basic Research and Development, Hiroshima University 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8530, Japan.
² Hydrolabo Inc., 3-10-31 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-0046, Japan.

Abstract

Zirconium phosphate-absorbed ammonia gas and the ammonia concentration (pressure) decreased to 2 ppm (ca. 20 Pa). However, it has not been clarified what the equilibrium pressure of zirconium phosphate is during ammonia gas ab/desorption. In this study, the equilibrium pressure of zirconium phosphate during ammonia ab/desorption was measured using cavity ring-down spectroscopy (CRDS). For ammonia-absorbed zirconium phosphate, a two-step equilibrium plateau pressure was observed during the ammonia desorption in gas. The value of the higher equilibrium plateau pressure at the desorption process was about 25 mPa at room temperature. If the standard entropy change (ΔS⁰) of the desorption process is assumed to be equal to the standard molar entropy of ammonia gas (192.77 J/mol_(NH₃)/K), the standard enthalpy change (ΔH⁰) is about -95 kJ/mol_(NH₃). In addition, we observed hysteresis in zirconium phosphate at different equilibrium pressures during ammonia desorption and absorption. Finally, the CRDS system allows the ammonia equilibrium pressure of a material in the presence of water vapor equilibrium pressure, which cannot be measured by the Sievert-type method.