Study of the Microstructure of Coal at Different Temperatures and Quantitative Fractal Characterization

Yong-Liang Xu; Xing-Wang Huo; Lan-Yun Wang; Xiang-Jun Gong; Ze-Cheng Lv; Tian Zhao

doi:10.1021/acsomega.3c02480

Study of the Microstructure of Coal at Different Temperatures and Quantitative Fractal Characterization

ACS Omega. 2023 Jun 12;8(25):23098-23111. doi: 10.1021/acsomega.3c02480. eCollection 2023 Jun 27.

Authors

Yong-Liang Xu^{1

2

3}, Xing-Wang Huo^{1

2

3}, Lan-Yun Wang^{1

2

3}, Xiang-Jun Gong^{1

2

3}, Ze-Cheng Lv^{1

2

3}, Tian Zhao^{1

2

3}

Affiliations

¹ School of Safety Science and Engineering, Henan Polytechnic University (HPU), Jiaozuo 454003, China.
² State Key Laboratory Cultivation Base for Gas Geology & Gas Control of HPU, Jiaozuo 454003, China.
³ Collaborative Innovation Center for Coal Safety Production & High-Efficient-Clean Utilization, Jiaozuo 454003, China.

Abstract

In order to understand the influence of underground coal fires on coal fractures and pores, mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM) are combined to study the development of coal pore and fracture under high-temperature treatment and calculate the fractal dimension to analyze the relationship between the development of coal pore and fracture and the fractal dimension. The results show that the volume of pores and fractures of the coal sample (C200) treated at 200 °C (0.1715 mL/g) is greater than that of the coal sample (C400) treated at 400 °C (0.1209 mL/g), and both are greater than the original coal sample (RC) (0.1135 mL/g). The volume increase is mainly due to mesopores and macropores, and the proportions of mesopores and macropores in C200 were 70.15 and 59.97% in C400. The MIP fractal dimension shows a decreasing trend with the increase of temperature, and the connectivity of coal samples improved with the increase of temperature. The changes in volume and three-dimensional fractal dimension of C200 and C400 showed the opposite trend and are related to the different stress of coal matrix at different temperatures. The experimental SEM images confirm that the connectivity of coal fractures and pores improves with the increase of temperature. Based on the SEM experiment, the larger the fractal dimension, the more complex the surface is. The SEM surface fractal dimensions indicate that the surface fractal dimension of C200 is the smallest and that of C400 is the largest, which is consistent with the observations made by SEM. The combination of the two fractal dimensions is used to characterize the self-similarity of coal using the fractal dimension difference. When the temperature increased to 200 °C, the unordered expansion of the coal sample resulted in the largest fractal dimension difference and the lowest self-similarity. When heated to 400 °C, the fractal dimension difference of the coal sample is the smallest, and the microstructure of coal shows a regular groove-like development.