From High Strain Rates to Elevated Temperatures: Investigating Mixed-Mode Fracture Behaviour in a Polyurethane Adhesive

Polymers (Basel). 2023 Jun 14;15(12):2675. doi: 10.3390/polym15122675.

Abstract

The investigation of the behaviour of adhesive joints under high strain rates is an active area of research, primarily due to the widespread use of adhesives in various industries, including automotive manufacturing. Understanding how adhesives perform when subjected to high strain rates is crucial for designing vehicle structures. Additionally, it is particularly important to comprehend the behaviour of adhesive joints when exposed to elevated temperatures. Therefore, this study aims to analyse the impact of strain rate and temperature on the mixed-mode fracture characteristics of a polyurethane adhesive. To achieve this, mixed-mode bending tests were conducted on test specimens. These specimens were subjected to three different strain rates (0.2 mm/min, 200 mm/min, and 6000 mm/min) and tested at temperatures ranging from -30 °C to 60 °C. The crack size was measured using a compliance-based method during the tests. For temperatures above Tg, the maximum load supported by the specimen increased with an increasing loading rate. GI increased by a factor of 35 for an intermediate strain rate and 38 for a high strain rate from low temperature (-30 °C) to room temperature (23 °C). GII also increased for the same conditions by a factor of 25 and 95 times, respectively.

Keywords: fracture energy; loading rate; mixed-mode; polyurethane adhesive; temperature.

Grants and funding

The second author acknowledges the individual grant No. 2020.04017.CEECIND, funded by national funds through the Portuguese Foundation for Science and Technology (FCT).